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张安运

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张安运工学博士、教授、博士生导师
化学工程与生物工程学系
杭州市浙大路38号,浙江大学
Tel./Fax0571-87953919O
 
1986年毕业于陕西师范大学化学系,1991年获西北大学硕士学位,1998年获中国原子能科学研究院博士学位,2000-2006年先后于日本原子力研究所(JAERI)日本产业创造研究所(IRI)Research Fellow研究员,2005年于日本产业创造研究所晋升为主任研究员,2006.4浙江大学教授、博士生导师、分子工程研究室主任,担任浙江省自然科学高级职称评定委员会委员、Open Inorg. Chem. J.Open Chem. Eng. J.Ion Exch. Lett.Res. J. Chem. Environ.4份国际刊物编委。
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从事多学科交叉领域研究,主要涉及:大环超分子识别试剂Calix[n]arene-Crown、多N多环Pyridine软配体试剂合成,先进大孔硅基超分子识别材料制备、分子修饰技术、溶剂萃取性能与机理、吸附科学与技术、色谱分离新技术新方法、化学反应动力学、自由基化学、量子化学计算及其应用、环境科学、制药工程、乏燃料后处理以及高放废物(HLLW)处理处置等一系列国际前沿领域研究。
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先后承担3项日本文部科学省课题、10余项日本原子力研究开发机构(JAEA)课题、以及中国国家自然科学基金、教育部博士学科点专项科研基金、教育部留学回国人员科研启动基金、钱江人才计划项目、浙江省自然科学基金等20余项研究课题。2006.4回国以来,主持2项国家自然科学基金及1博士点基金等8项课题,授权英法美日国际发明专利5项,申请中国发明专利8项,在国内外学术刊物上发表研究论文100余篇,其中在SCI源刊上发表论文50余篇。与美国、日本和欧洲等多所大学及研究机构有良好的合作关系。
 
研究团队
本实验室现有教授2名、博士生导师2名,博士生和硕士生7名,中国科学院柴之芳院士为本实验室浙江大学“求是”讲座教授,并从20089月起招收博士研究生及博士后研究人员。
 
研究兴趣
1. 新颖Calix[n]arene-Crown超分子识别试剂合成
2. N多环含软原子R-BTP系列有机试剂合成
3. 先进反应性与功能性大孔硅基超分子识别材料制备
4. 吸附-色谱分离新技术新方法
5. 溶剂萃取性能和机理
6. 各种吸附过程及氧化还原反应动力学与机理
7. 新型配合物合成与表征
 
承担课题
1. 国家自然科学基金(2009-2011)新颖固定化灌注型大孔硅基反应性与功能性材料次锕系元素分离新技术新方法
2. 国家自然科学基金(2007-2009)基于新型固定化灌注型硅基超分子识别材料发热元素锶铯分离新技术新方法
3. 教育部博士学科点科研基金(2008-2010):新颖固定化灌注型大孔硅基超分子识别材料色谱分离发热元素基础特性研究
4. 教育部留学回国人员科研启动基金(2008-2011)
5. “钱江人才计划项目(2006-2007)
6. 浙江省自然科学基金(2006-2009)
 
热忱欢迎无机化学、有机化学、物理化学、应用化学、计算化学、制药工程、化学工程、材料化学、高分子化学、核化学化工或放射化学背景、有意继续深造的莘莘学子加盟本研究团队,攻读硕士/博士学位或从事博士后研究。
 
代表性论文
1.         Anyun Zhang, Chunmei Chen, Etsushu Kuraoka, Mikio Kumagai, Impregnation Synthesis of a Novel Macroporous Silica-Based Crown Ether Polymeric Material Modified by 1-Dodecanol and Its Adsorption for Strontium and Some Coexistent Metals. Separation and Purification Technology, 2008, 62(2), 407-414.
2.         Anyun Zhang, Weihong Wang, Zhifang Chai, Mikio Kumagai, Separation of Strontium Ions from a Simulated Highly Active Liquid Waste Using a Composite of Silica-Crown Ether in a Polymer. J. Separation Science, 2008, 31(18), 3148-3155.
3.         Anyun Zhang, Chunmei Chen, Weihong Wang, Yuezhou Wei, Adsorption Behavior of Sr(II) and Some Typical Co-existent Metals Contained in High Level Liquid Waste onto a Modified Macroporous Silica-Based Polymeric DtBuCH18C6 Composite. Solvent Extraction and Ion Exchange, 2008, 26(5), 624-642.
4.         Anyun Zhang, Weihong Wang, Zhifang Chai, Etsushu Kuraoka, Modification of a Novel Macroporous Silica-Based Crown Ether Impregnated Polymeric Composite with 1-Dodecanol and Its Adsorption for Some Fission and Non-Fission Products Contained in High Level Liquid Waste. European Polymer Journal, 2008, 44(11), 3899-3907.
5.         Anyun Zhang, Qihui Hu, Weihong Wang, Etsushu Kuraoka, Application of a Macroporous Silica-Based CMPO-Impregnated Polymeric Composite in Group Partitioning of Long-Lived Minor Actinides from Highly Active Liquid by Extraction Chromatography. Industrial & Engineering Chemistry Research, 2008, 47 (16), 6158–6165.
6.         Anyun Zhang, Etsushu Kuraoka, Mikio Kumagai, Development of the Chromatographic Partitioning of Cesium and Strontium Utilizing Two Macroporous Silica-Based Calix[4]arene-Crown and Amide Impregnated Polymeric Composites: PREC Separation Process. J. Chromatography A, 2007, 1157(1-2), 85-95.
7.         Anyun Zhang, Etsushu Kuraoka, Mikio Kumagai, Impregnation Synthesis of a Novel Macroporous Silica-Based TODGA Polymeric Composite and Its Application in the Adsorption of Rare Earths in Nitric Acid Solution Containing Diethylenetriaminepentaacetic Acid. European Polymer Journal, 2007, 43(2), 529-539.
8.         Anyun Zhang, Etsushu Kuraoka, Mikio Kumagai, Group Partitioning of Minor Actinides and Rare Earths from Highly Active Liquid Waste by Extraction Chromatography Utilizing Two Macroporous Silica-Based Impregnated Polymeric Composites. Separation and Purification Technology, 2007, 54(3), 363-372.
9.         Anyun Zhang, Yuezhou Wei, Harutaka Hoshi, Yoshikazu Koma, Masayoshi Kamiya, Partitioning of Cesium from a Simulated High Level Liquid Waste by Extraction Chromatography Utilizing a Macroporous Silica-Based Supramolecular Calix[4]arene-crown Impregnated Polymeric Composite. Solvent Extr. Ion Exch., 2007, 25(1), 1-17.
10.     Anyun Zhang, Chengliang Xiao, Etsushu Kuraoka, Mikio Kumagai, Preparation of a Novel Silica-Based DtBuCH18C6 Impregnated Polymeric Composite Modified by Tri-n-Butyl Phosphate and Its Application in Chromatographic Partitioning of Strontium from High Level Liquid Waste. Industrial & Engineering Chemistry Research, 2007, 46(7), 2164-2171.
11.     Anyun Zhang, Chengliang Xiao, Etsushu Kuraoka, Mikio Kumagai, Molecular Modification of a Novel Macroporous Silica-Based Impregnated Polymeric Composite by Tri-n-Butyl Phosphate and Its Application in the Adsorption for Some Metals Contained in a Typical Simulated HLLW. J. Hazardous Materials, 2007, 147(1-2), 601-609.
12.     Anyun Zhang, Yuezhou Wei, Mikio Kumagai, Separation of Minor Actinides and Rare Earths from a Simulated High Activity Liquid Waste by Two Macroporous Silica-based Polymeric Composites. Sep. Sci. Technol., 2007, 42(10), 2235-2253.
13.     Anyun Zhang, Etsushu Kuraoka, Mikio Kumagai, Preparation of a Novel Macroporous Silica-Based 2,6-Bis(5,6-Diisobutyl-1,2,4-Triazine-3-yl)Pyridine Impregnated Polymeric Composite and Its Application in the Adsorption for Trivalent Rare Earths. J. Radioanal. Nucl. Chem., 2007, 274(3), 455-464.
14.     Anyun Zhang, Chunmei Chen, Yuezhou Wei, Mikio Kumagai, Preparation of a Novel Macroporous Silica-Based Diglycolamide Derivative Impregnated Polymeric Composite and Its Adsorption Mechanism for Rare Earth. Adsorption Science and Technology, 2007, 25(5), 257-272.
15.     Anyun Zhang, Yuezhou Wei, Tsuyoshi Arai, Mikio Kumagai, Palladium Removal from the Simulated Nuclear Spent Fuel Solution Using a Silica-Based SiPyR-N3 Anion Exchanger. Solvent Extr. Ion Exch., 2006, 24 (3), 447-462.
16.     Anyun Zhang, Etsushu Kuraoka, Mikio Kumagai, Yoshikazu Koma, Tomozo Koyama, Synthesis and Application of Macroporous Silica-Based Octyl(phenyl)-N,N-Diisonutylcarbamoylmethylphosphine Oxide Functional Polymeric Composite in Chromatographic Partitioning of High Level Liquid Waste. J. Radioanal. Nucl. Chem., 2006, 269(1), 119-128.
17.     Anyun Zhang, Kuraoka Etsushu, Mikio Kumagai, Removal of Pd(II), Zr(IV), Sr(II), Fe(III), and Mo(VI) from Simulated High Level Liquid Waste by Extraction Chromatography Utilizing the Macroporous Silica-Based Polymeric Materials. Separation and Purification Technology, 2006, 50(1), 35-44.
18.     Anyun Zhang, Gunzo Uchiyama, Toshihide Asakura. pH Effect on Uranium(VI) Adsorption from Seawater by a Macroporous Fibrous Polymeric Material Containing Amidoxime Functional Group. Reactive and Functional Polymers, 2005, 63(2), 143-153.
19.     Anyun Zhang, Yuezhou Wei, Harataka Hoshi,Mikio Kumagai, Synthesis of a Novel Silica-Based Macroporous Polymer Containing TODGA Chelating Agent and Its Application in the Chromatographic Separation of Mo(VI) and Zr(IV) from Diethylenetriaminepentaacetic Acid. Sep. Sci. Technol., 2005, 40(4), 811-827.
20.     Anyun Zhang, Yuezhou Wei, Mikio Kumagai, Yoshikazu Koma. A New Partitioning Process for High Level Liquid Waste by Extraction Chromatography Using Silica-Substrate Chelating Agent Impregnated Adsorbents. Journal of Alloys and Compounds, 2005, 390(1-2), 275-281.
21.     Anyun Zhang, Yuezhou Wei, Mikio Kumagai, Yoshikazu Koma, Tomozo Koyama, Resistant Behavior of a Novel Silica-Based Octyl(phenyl)-N,N-diisobutylcarbamoylmethylphoshine Oxide NeutralExtraction Resin AgainstNitric Acid, Temperature and g-Radiation. Radiation Physics and Chemistry, 2005, 72(4), 455-463.
22.     Anyun Zhang, Yuezhou Wei, Harutaka Hoshi, Mikio Kumagai, Masayoshi Kamiya, Tomozo Koyama, Resistance Properties of a Macroporous Silica-Based N,N,N′,N′-Tetraoctyl-3-Oxapentane-1,5- Diamide Impregnated Polymeric Adsorption Material Against Nitric Acid, Temperature and g-Irradiation. Radiation Physics and Chemistry, 2005, 72(6), 669-678.
23.     Anyun Zhang, Yuezhou Wei, Harataka Hoshi, Mikio Kumagai, Chromatographic Separation of Strontium (II) from a Nitric Acid Solution Containing Some Typically Simulated Elements by a Novel Silica-Based TODGA Impregnated Polymeric Composite in MAREC Process. Solvent Extr. Ion Exch., 2005, 23(2), 231-247.
24.     Anyun Zhang, Yuezhou Wei, Harataka Hoshi, Mikio Kumagai, Yoshikazu Koma, Leakage of Octyl(phenyl)- N,N-Diisobutylcarbamoylmethylphoshine Oxide from a Macroporous Silica-Based Chelating Polymeric Adsorption Material and Its Recovery by Some Selected Porous Adsorbents. Adsorption Science and Technology, 2005, 23(9), 721-737.
25.     Anyun Zhang, Yuezhou Wei, Mikio Kumagai, Bleeding Evaluation of the Stationary Phase from a Few Novel Macroporous Silica-SubstratePolymeric Materials Used for Radionuclides Partitioning from HLLW in MAREC Process. J. Radioanal. Nucl. Chem., 2005, 265(3), 409-417.
26.     Anyun Zhang, Kuraoka Etsusyo, Harataka Hoshi, Mikio Kumagai, Synthesis of Two Novel Macroporous Silica-Based Impregnated Polymeric Composites and Their Application in Highly Active Liquid Waste Partitioning by Extraction Chromatography. J. Chromatography A, 2004, 1061(2), 175-182.
27.     Anyun Zhang, Yuezhou Wei, Mikio Kumagai, Tomozo Koyama, Kinetic of the Adsorption of Strontium(II) by a Novel Silica-Based 4,4,(5)-Di-(Tert-Butylcyclohexano)-18-crown-6 Extraction Resin in Nitric Acid Medium. J. Radioanal. Nuch. Chem., 2004, 262(3),739- 744.
28.     Anyun Zhang, Wanyan Guanghui, Mikio Kumagai, Association Behavior of 4-Acylpyrazolone Derivative and Tertiary Amine of High Molecular Weight in Antagonistic Synergistic Extraction of Palladium. J. Solution Chemistry, 2004, 33(8), 1017-1028.
29.     Anyun Zhang, Yuezhou Wei, Harataka Hoshi, Mikio Kumagai, Adsorption and Chromatographic Separation of Mo(VI) and Zr(IV) Ions from a High-concentration Oxalic Acid Solution by a Macroporous Silica-based N,N,N,N-Tetraoctyl-3-Oxapentane-1,5-Diamide Polymeric Adsorbent. Adsorption Science and Technology, 2004, 22(6), 497-509.
30.     Anyun Zhang, Yuezhou Wei, Mikio Kumagai, Synthesis of A Novel Macroporous Silica-Based Polymeric Material Containing 4,4,(5)-Di(Tert-Butylcyclohexano)-18-Crown-6 Functional Group and Its Adsorption Mechanism for Strontium. Reactive and Functional Polymers, 2004, 61(2), 191-202.
31.     Anyun Zhang, Kai Li, Jingxin Hu, Hydroxylamine Derivatives in Purex Process. Part VIII. Kinetics and Mechanism of the Redox Reaction of N-Methylhydroxylamine and Vanadium(V). J. Radioanal. Nucl. Chem., 2004, 261(2), 301-307.
32.     Anyun Zhang, Wanyan Guanghui, Mikio Kumagai, Extraction Chemistry of Palladium(II). Mechanism of Antagonistic Synergistic Extraction of Palladium by 4-Aroyl Derivative of 1-Phenyl-3-Methyl-Pyrazolone- 5-One and Trialkylamine of High Molecular Weight. Transition Metal Chemistry, 2004, 29(5), 571-576.
33.     Yuezhou Wei, Anyun Zhang, Mikio Kumagai, Masayuki Watanabe, Naoto Hayashi, Development of the MAREC Process for HLLW Partitioning Using a Novel Silica-based CMPO Extraction Resin. J. Nucl. Sci. Technol., 2004, 41(3), 315-322.